Sigma-Aldrich
Chloroform-D, 99.8 atom% D, 1 kg
- Part Number:
- MIL-151823-1KG
- Lead Time:
- 7-14 days
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- Quantity:
- each
- Size:
- 1 kg
- Style:
- chemical
- DOT Rated:
- HazMat Transport Fee Required
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Description
Chloroform-D, 99.8 atom% D, 1 kg
Chloroform-D 99.8 Atom% D 1 Kg
Synonym: Deuterochloroform
General description
Chloroform-d (Deuterochloroform, CDCl3), deuterated chloroform, is a standard purity solvent for NMR (Nuclear Magnetic Resonance) analyses. It is widely employed in high resolution NMR studies due to its high chemical and isotopic purity. Quantitative infrared spectral investigations of carbon-deuterium stretching bands of chloroform-d in various organic solvents have been reported. Raman difference spectroscopic studies of mixtures of chloroform-d and liquid chloroform have been conducted to evaluate frequency shifts in the ν1 and ν2 bands of CHCl3 and CDCl3.
Application
Chloroform-d has been employed as solvent in a 1H NMR (Proton Nuclear Magnetic Resonance) spectroscopic study. It has been employed as solvent during the 31PNMR (Phosphorus-31 nuclear magnetic resonance) spectral investigation of triphenyl phosphate and tris(2-chloroethyl) phosphate. It has also been used as the deuterated solvent in the 1H NMR spectral studies of 2-(4-bromobenzyl)-3-hydroxypropanoic acid and 3-hydroxy-2-(4-methoxybenzyl)propanoic acid. It has also been used as the deuterated solvent for the 1HNMR spectral studies of 3,3′-dihydroxy-4,4′-diamino-biphenyl (HAB) and 2,2′-bis-(3,4-dicarboxy-phenyl) hexafluoropropane dianhydride (6FDA) polyimide.
Specifications
- CAS Number 865-49-6
- Linear Formula CDCl3
- Molecular Weight 120.38
- Beilstein/REAXYS Number 1697633
- EC Number 212-742-4
- MDL number MFCD00000827
- PubChem Substance ID 24849167
- NACRES NA.21
- UNSPSC Code 12142201
| InChI Key | HEDRZPFGACZZDS-MICDWDOJSA-N |
| Isotopic Purity | 99.8 atom % D |
| Assay | Assay |
| Refractive Index | n20/D 1.444 (lit.) |
| bp | 60.9°C (lit.) |
| mp | −64°C (lit.) |
| Density | 1.500 g/mL at 25°C (lit.) |
| Mass Shift | M+1 |
| Quality Level | 200 |
| Form | liquid |
| Technique(s) | NMR: suitable |
| SMILES string | [2H]C(Cl)(Cl)Cl |
| InChI | 1S/CHCl3/c2-1(3)4/h1H/i1D |
| Pictograms | GHS06, GHS08 |
| Signal word | Danger |
| Hazard statements | H302-H315-H319-H331-H351-H361d-H372 |
| Precautionary statements | P260-P280-P301 + P312 + P330-P304 + P340 + P312-P305 + P351 + P338-P403 + P233 |
| Personal Protective Equipment | Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US) |
| RIDADR | UN 1888 6.1 / PGIII |
| WGK | WGK 3 |
Legal Information
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Documents
WARNING: This product can expose you to chemicals which are known to the State of California to cause cancer and reproductive harm. Prop 65 Warning
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